Grand distribution
WebSep 19, 2024 · Now, using the general Equation ( 2.2.11) to calculate the entropy for the distribution ( 2.7.5) (exactly like we did it for the canonical ensemble), we get the following expression, S = − ∑ m, NWm, NlnWm, N = E T − μ N T + lnZG, which is evidently a generalization of Equation ( 2.4.12 ). 62 We see that now the grand thermodynamic ... WebThe grand canonical partition function applies to a grand canonical ensemble, ... As an example: the partition function for the isothermal-isobaric ensemble, the generalized Boltzmann distribution, divides up probabilities based …
Grand distribution
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